Galvanic Corrosion guessing game
Here is a very short paper by Prof Stephen C. Dexter from the University of Delaware Sea Grant Program. Short but compact with implications. Obviously I'm fascinated by the subject - and there are many commonly held misconceptions this read might start to unravel. Including my own!
This paper has a revealing galvanic series table referenced 'in flowing seawater'.
Which is exactly where we want to be when discussing the problem.
Manganese bronze and silicon bronze are cheek by jowl with each other in the table having a close voltage range. Here I discover the 300 s.s. are closer to the cathodic or noble end of the series.
So my assumption that copper alloys are more noble than stainless is WRONG.
Stainless has more problems than bronze like crevice corrosion and changing voltages when covered with slime.
And I might add, that while the voltage range is amazingly close with M.B. and S.B., the one overloaded with zinc is more prone to falling apart than the nearly pure copper alloy.
This table shows why we do not want 300 steel in our bronze shoe. And it explains the phenomena I saw on my Ariel's rudder shoe.
It also shows the surprising over-lapping voltage range between manganese bronze and silicon bronze. Either one can be anode or cathode in a galvanic couple "depending on exact exposure conditions." So that's a good reason to add a third more anodic metal in the form of zinc - if you have that going with those two..... M. bronze shoe and S. bronze shaft, or......
Galvanic Corrosion Final
www.ocean.udel.edu/mas/masnotes/corrosion.pdf
plasticizing an old rudder
gotta listen to bill on this.
5200 in the metal to wood seams if you are launching now is a good call.
Depending on how much water is still 'logged' in the wood of a rudder, it could conceivably be successful to GLASS a rudder with a few layers of CLOTH and EPOXY. Arguably the wood is still swelled throughout most of its interior and is 'equalized'. If the water content in the wood was close to 20%, but the surface dry enough for regular epoxy laminations, who's to say it wouldn't work?
If your rudder there in the photos has been very dry, back in the water the swelling of the wood WILL crack the thickened epoxy. There is always the exception, the stuff may not crack because the rudder is old enough to be almost inert. The blade is also well shaped and thin enough to be successfully subdued with frp but not gelled epoxy.
Baking the planks in the sun would, could shrink and loosen it up and open up the surface radically. And immersion in water will tighten it up. Swell seams closed again. And reduce the wobble of the planks on their bolts. Wood is amazing.
In my book the only certain useful epoxy on an old plank rudder is to dress the wood in penetrating epoxy. No more than two coats, loading creates a gummy mess. Goes for a brand new one also. The commercial stuff is very flexible and would not contest the movement of the wood. It would be a sealer and provide a better base for epoxy primer and bottom paint. And add worm protection. You can make a credible penetrating sealer by thinning combined two-part laminating epoxy with xylene.
If you are going to use the present rudder as is - as a core for fiberglassing - you will have to put many layers of cloth to defeat the core's swelling. It may be nearly impossible.
If you strip the old mahogany from the shafts, you could replace it with plywood. The method is described here in this thread. (see pg 11, 153>) But does not describe the glassing step.
You'd rout in coves where the bolts are and sandwich them between two layers of meranti-aguaply. You may not need even to remove the bolts from the shaft. Then apply glass cloth around well prepared bronze rod and
shaped ply. Ply is not going to swell like planks.
[What countless skippers (well, maybe they could be counted:p) have discovered is that both polyester and epoxy allow moisture and or water vapor to enter what the plastics are covering. Depending on how thorough the glass job, it's only a matter of time.
The rudder with the least future problems has a closed cell pvc foam core.]
What's good about this plywood method is that you can use what you have - if the metal is in good condition - and end up with another 40year rudder. Your investment is in the plywood, epoxy and cloth.
imco, ebb